Radiation Induced Colour Centres In Multicomponent Glasses

This paper discusses, in some detail, the nature of colour centres induced by radiation in different borate, silicate and phosphate glasses; using optical and ESR techniques. The role of cerium and other multi valent ions in suppression of some of these centres and in studying their nature is also discussed. In most glasses, the visible induced absorption was associated with positive hole centres. However, at certain compositions, an electron trap centre which absorbs in the visible is also induced by radiation, and was associated with certain structural defects, e.g. a non-bridging oxygen ion vacancy neighbouring the alkali ions in diborate or disilicate glasses, Pb2+ ions (or other iso electronic ions) taking network modifying positions, or Ce3+ ions in relatively high concentrations.

Author
A Bishay
Origin
American University In Cairo, Egypt
Journal Title
J Non Cryst Solids 3 1970 54-114
Sector
Primary Papers
Class
PP 102

Request article (free for British Glass members)

Radiation Induced Colour Centres In Multicomponent Glasses
J Non Cryst Solids 3 1970 54-114
PP 102
Are you a member?
This question is for testing whether or not you are a human visitor and to prevent automated spam submissions.
2 + 5 =
Solve this simple math problem and enter the result. E.g. for 1+3, enter 4.