The main propositions and relationships of valence-configurational theory of viscous flow in super-cooled glass-forming liquids have been formulated. It is shown that, within the limits of the formalism of the theory of absolute reaction rates, the activation entropy of viscous flow corresponds to the configurationally changes in some local region around the switched bonds.
Origin
Unknown
Journal Title
The Soviet Chemistry 1978 4 (2) 113-129
Sector
Primary Papers
Class
PP 586